Kissinger equation

  • 释义

    基辛格方程式

数据更新时间:2025-12-22 17:55:22
1、

The Ozawa's and Kissinger's equation were employed for the kinetic parameters of the thermal oxidation reaction of DHA and EPA glycerides, whose results were coherent.

用Ozawa法和Kissinger法计算DHA和EPA甘油酯的热氧化反应动力学参数,两种计算方法得到的动力学参数具有一致性。

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2、

The curing kinetics of the vinyl ester resin used in pultrusion process was studied by non-isothermal DSC test, and the apparent activation energy(Δ E) and the reaction order ( n) of the curing reaction were calculated by using the Kissinger and Crane equation.

采用非等温DSC法研究了适合于拉挤工艺的乙烯基酯树脂体系固化反应动力学,用Kissinger方程和Crane方程求得树脂体系固化反应的表观活化能为68.3kJ/mol,反应级数为0.918。

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3、

The cure kinetic equations were deduced from Kissinger equation and Ozawa Flynn Wall equation, by which the mathematical technique used to evaluate the parameters of the cure kinetics, the reaction order and activation energy.

分别用Kissinger方程和Ozawa-Flynn-Wall方程推导了该固化体系的固化动力学方程,并计算了固化反应活化能。

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4、

Besides, thermodynamic analysis was made to the curing reaction of glucose-phenol resin adhesive by TGA and DSC, Kissinger equation and Crane equation were used to calculate the dynamic parameters of the curing reaction.

除此以外,我们还通过TGA、DSC对葡萄糖苯酚树脂的固化反应进行了热力学分析,利用Kissinger方程和Crane公式计算了树脂固化反应的动力学参数。

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5、

This isothermal crystallization kinetics of PP/ talc composites was treated using Avrami equation and the effect of talc on the crystallization activation energy was treated using Kissinger equation.

用Avrami方程全面分析PP/滑石粉的等温结晶动力学,并由此获得相关的动力学参数;用Kissinger方程研究滑石粉对PP/滑石粉复合材料结晶活化能的影响。

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6、

Moreover, the activation energy is estimated to be 1.1 eV based on the Kissinger equation, which is two times than Cu/ SiO2 ( 0.6 eV), suggesting that inserting Ni-Al-N barrier can improve failure temperature and the stability of interconnect structure.

计算样品失效激活能为1.1eV,几乎是Cu/SiO2的激活能(0.6eV)2倍,表明Ni-Al-N阻挡层的插入可以提高失效温度与互连线结构的热稳定性。

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7、

The degradation kinetics of CSM was studied by Ozawa and Kissinger equation. The thermal degradation of CSM was not a first order reaction. With the increase of heating rate ( P), the temperature of degradation is rising gradually.

采用Ozawa及Kissinger方程研究了氯磺化聚乙烯的降解动力学,随着升温速率的增大,降解的起始温度升高。

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8、

The apparent activation energy and the order of reaction were calculated by Kissinger equation and Flynn-Wall-Ozawa equation respectively.

分别用Kissinger方法和Flynn-Wall-Ozawa方法计算固化反应的表观活化能和反应级数。

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9、

The effects of hydrogen on the activation energy and the kinetics of glass transition and crystallization of Zr-Ti-Cu-Ni-Be bulk amorphous alloy were studied by differential scanning calorimetry ( DSC) and the Kissinger equation.

利用非等温差热扫描量热分析方法及Kissinger方程,研究了H原子对Zr-Ti-Cu-Ni-Be块状非晶合金玻璃转变和晶化的激活能影响。

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10、

The curing kinetic parameters of the modified systems were obtained by the Kissinger's equation and Crane's equation.

利用Kissinger方程和Crane方程求出了改性体系的固化动力学参数。

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11、

The average crystallization activation energies of hexagonal and monoclinic structures of trans 1,4-polybutadiene were obtained by Kissinger equation to be-165.8 kJ/ mol,-220.5 kJ/ mol, respectively.

由Kissinger方程得到TPBD六方相和单斜相结晶的平均结晶活化能分别为-165.8kJ/mol和-220.5kJ/mol。

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12、

It also studied cure kinetic characteristics through programmed heating DSC method and Kissinger equation, and obtained some important kinetic parameters, such as the apparent activation energy and order of reaction etc.

采用程序升温DSC法,用Kissinger方程研究了PPO/EP体系的动力学特征,并计算得到了一些重要的动力学参数如表观活化能、反应级数等。

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